{"id":82,"date":"2024-05-30T07:55:29","date_gmt":"2024-05-29T23:55:29","guid":{"rendered":"https:\/\/aluminaceramics.net\/?p=82"},"modified":"2024-07-15T20:22:29","modified_gmt":"2024-07-15T12:22:29","slug":"alumina-formula","status":"publish","type":"post","link":"https:\/\/aluminaceramics.net\/pt\/alumina-formula\/","title":{"rendered":"F\u00f3rmula de alumina"},"content":{"rendered":"<p>Aluminum oxide (Al2O3), also referred to as alumina, is an electrical insulator with excellent chemical resistance and moderate tensile and flexural strengths; however, its flexural toughness remains low.<\/p>\n<p>Alumina is the go-to material when it comes to oxide ceramics due to its abundance, low cost and superior mechanical properties over other oxides.<\/p>\n<h2>Chemical Formula<\/h2>\n<p>Aluminum oxide (more commonly referred to as alumina or alundum) is an inorganic chemical compound with the formula Al2O3 that features high melting point and strong hardness, white colour, insoluble in water and amphoteric properties &#8211; reacting both acidically and alkaliney &#8211; making it one of the most popular industrial ceramics. Alumina occurs naturally as corundum, rubies and sapphires as well as being present as its principal aluminium ore in bauxite while production methods include chemically dehydration of an aluminate solution or chemical dehydration of an aluminate solution.<\/p>\n<p>Alumina is widely used to line high-temperature appliances like kilns, furnaces and incinerators due to its thermal and electrical insulation properties as well as resistance against corrosion caused by chemicals used during manufacturing processes. Alumina offers excellent thermal and electrical insulation properties as well as protection from corrosion; making it the ideal material choice.<\/p>\n<p>Alumina is one of the hardest engineered materials, rivaling diamond in hardness and second only to silicon carbide for wear resistance. Furthermore, alumina acts as an excellent insulator and has a low expansion coefficient that ensures heat transfer occurs efficiently and predictably.<\/p>\n<p>Corundum, the most stable polymorph of alumina, is one of its stablest forms. It possesses a trigonal Bravais lattice structure in which oxygen ions occupy layers parallel to its c-axis while aluminum fills two thirds of octahedral interstices. Corundum&#8217;s ratio of oxygen ions: aluminum ions is 1:2:1.<\/p>\n<p>Crystalline alumina is an economical material with low specific gravity and hardness, typically found as powder with particle sizes between 0.3 and 0.8 mm. There are two forms of crystalline alumina powder; type A contains hexagonal crystals and has a density of 4.0, while type B features cubic crystals at 3.0 density; both exhibit good abrasion resistance with type A cutting faster.<\/p>\n<p>At 94% purity, alumina can be produced, although most commercial applications typically call for purities of between 85%-100%. Lower purity grades are commonly used in refractory applications while higher-purity grades can be found in zirconia toughened alumina (ZTA) ceramics or monolithic ceramics such as hard and dense ZTA grades.<\/p>\n<h2>Physical Properties<\/h2>\n<p>Aluminium oxide (Al2O3), commonly referred to as alumina, is an ionic-covalent solid that does not yield under load like metals and alloys do. Alumina&#8217;s low electric conductivity and thermal stability make it an excellent insulator, with excellent resistance against chemical attack and extreme hardness (9 on Mohs scale). Due to its high melting point, casting it isn&#8217;t feasible but its strength, durability and corrosion-resistance make it suitable for use in harsh processing environments like kilns and furnaces.<\/p>\n<p>Ceramic linings composed of alumina are widely utilized as blast furnace linings to protect metal nozzles and lances, refractory liners for steel kilns and rotary kilns, as well as castable refractory brick casting sand casting processes. Alumina has a low coefficient of expansion which allows it to withstand very high temperatures without warping or cracking; furthermore it is resistant to acid attack, as evidenced by its success as an electrical wire insulation application insulator in harsh electrical applications such as copper wire applications corrosive environments.<\/p>\n<p>Alumina&#8217;s high melting point makes it an ideal refractory material for glass manufacturing, where only trace amounts of Al2O3 exist in many window and container glasses. If these glasses were used as glazes they would run and crack due to lack of sufficient refractory elements in their composition.<\/p>\n<p>However, adding even a small amount of alumina to a glass recipe enables it to melt at a lower temperature while improving tensile strength, surface tension, luster, length of working range devitrification resistance and toughness. Furthermore, adding just a pinch increases flexural and tensile strengths and reduces brittle fracture behavior significantly.<\/p>\n<p>Refractory properties of alumina make it an excellent candidate for use as medical alumina, used for dental implants and other biomedical applications. Medical alumina is produced using various consolidation and sintering techniques that produce precise near-net shapes with wide purity ranges. While its moderate tensile\/bending strength falls below that required of polycrystalline alumina implants for implant applications, its superior mechanical performance still make this material worth consideration for medical applications.<\/p>\n<h2>Thermal Properties<\/h2>\n<p>Alumina stands out from other metals or alloys by virtue of its strong interatomic bonding, giving it unique properties not seen elsewhere, including high strength and hardness, excellent dielectric properties at both low and elevated temperatures, excellent resistance to chemical attack and corrosion at both room and elevated temperatures, superior thermal properties at high temperatures, as well as providing an efficient heat sink solution.<\/p>\n<p>Alumina comes in several forms including granular, powder and slurries and can be formed into any variety of shapes. With moderate tensile strength and bend bending strength, Alumina differs from many polycrystalline ceramic materials in that its thermal conductivity and melting point are relatively low &#8211; meaning casting large parts impossible.<\/p>\n<p>Alpha phase alumina (Al2O3) is the material most often employed for structural applications of alumina. This polycrystalline form features oxygen ions organized hexagonally close-packed, filling two-thirds of all the octahedral interstices. Alumina also shows metastability in cubic g and e phases, monoclinic k phase, and orthorhombic d phase which eventually all return back to stable hexagonal alpha phase at elevated temperatures.<\/p>\n<p>Pure alumina has many industrial uses and is typically supplied in the form of sodium aluminate with formula NaAlO. This material is produced by roasting bauxite at high temperatures to produce sodium aluminate, and then ground into fine powder prior to mixing with water to produce a slurry for further processing.<\/p>\n<p>Modern alumina products typically fall between 85%-100% purity levels, making it suitable for spark plugs and microchip substrates, as well as high performance ceramic applications like thick film coating.<\/p>\n<p>Pure alumina outperforms porcelain electrical insulation by at least two orders of magnitude at room temperatures and four orders at high temperatures, and is significantly less vulnerable to alkali attacks that cause degradation.<\/p>\n<h2>Mechanical Properties<\/h2>\n<p>Mechanical properties of alumina include its strength, or strain-stress tolerance. This property makes alumina ceramics highly resistant to shocks, keeping their shape and size even under intense pressure. Furthermore, alumina has high compressive strength for supporting heavy loads without becoming damaged while its tensile and bending strengths enable structural components and parts to remain intact and functional.<\/p>\n<p>Alumina boasts excellent mechanical properties, such as its durability and resistance to chemical attacks, making it suitable for industrial and commercial applications, including power plants and factories. As one of the most durable engineering ceramics available today, alumina can withstand extreme temperatures as well as wear-and-tear, making it an excellent material choice for manufacturing products like electrical insulators, gas laser tubes, seal rings and laboratory equipment.<\/p>\n<p>Alumina&#8217;s resistance to attack also makes it a sought-after material for producing protective armor, making it one of the go-to choices among military vehicle and personnel manufacturers. Alumina&#8217;s hardness and bioinertness prove particularly useful here; making it suitable for creating hip replacement bearings, bionic implants, tissue reinforcement, tissue scaffolding applications as well as medical use applications like hip replacement bearings. Furthermore, its durability also makes alumina an excellent choice when producing ballistic armor.<\/p>\n<p>Alumina ceramics offer low acute and chronic toxicities, producing only minor skin irritation in short exposure times, making it an ideal material for use in medical equipment and healthcare applications. Their non-reactivity with various chemicals makes alumina ceramics increasingly common as surgical instrument replacements such as tungsten carbide; but for optimal toughness requirements in medical alumina it must first undergo strict regulation during its sintering process.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-205\" src=\"https:\/\/aluminaceramics.net\/wp-content\/uploads\/2024\/05\/Alumina-Formula.jpg\" alt=\"F\u00f3rmula de alumina\" width=\"750\" height=\"750\" srcset=\"https:\/\/aluminaceramics.net\/wp-content\/uploads\/2024\/05\/Alumina-Formula.jpg 750w, https:\/\/aluminaceramics.net\/wp-content\/uploads\/2024\/05\/Alumina-Formula-300x300.jpg 300w, https:\/\/aluminaceramics.net\/wp-content\/uploads\/2024\/05\/Alumina-Formula-150x150.jpg 150w, https:\/\/aluminaceramics.net\/wp-content\/uploads\/2024\/05\/Alumina-Formula-12x12.jpg 12w\" sizes=\"auto, (max-width: 750px) 100vw, 750px\" \/><\/p>","protected":false},"excerpt":{"rendered":"<p>Aluminum oxide (Al2O3), also referred to as alumina, is an electrical insulator with excellent chemical resistance and moderate tensile and 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